Valeria Giuliani Scuola Normale Superiore Servizio alla Didattica e Allievi tel. 050 509260 Piazza dei Cavalieri, 7 56126 Pisa E-mail: valeria.giuliani@sns.it E-mail: classi@sns.it

---------- Forwarded message ---------- From: Valeria Giuliani valeria.giuliani@sns.it Date: 2018-01-25 10:10 GMT+01:00 Subject: avviso Colloquio della Classe di Scienze, prof. Patrick Vaccaro (31.01.2018) To: professori.sci@sns.it, "professori.contratto.sci" < professori.contratto.sci@sns.it>, ricercatori.sci@sns.it, ricercatori.td.sci@sns.it, Borsisti borsisti@sns.it, assegnisti.sci@sns.it, Perfezionandi Scienze phd.sci@sns.it, "phd.extra.sci" < phd.extra.sci@sns.it>, Studenti Scienze allievi.sci@sns.it, "allievi.extra.sci" allievi.extra.sci@sns.it, Esterni Scienze in Convenzione esterni_sci_inconvenzione@sns.it Cc: Classi classi@sns.it, Sito SNS sitosns@sns.it, Portineria Carovana < portineria.carovana@sns.it>

*Colloqui della Classe di Scienze*

Anno Accademico 2017/2018

Mercoledì 31 gennaio 2018

ore 15:00

*Scuola Normale Superiore*

Pisa

(Sala Azzurra)

*Patrick Vaccaro*

*(Department of Chemistry, Yale University, New Haven, CT USA)*

Terrà un seminario dal titolo:

*“Optical Rotatory Dispersion: New Twists on an Old Topic”*

*Abstract:*

Among the many physicochemical properties that distinguish chiral molecules, perhaps none has had as profound an impact upon chemistry as the characteristic interactions taking place with polarized light – phenomena collectively known as optical activity. Efforts to probe the dispersive (non-resonant) components of such spectral signatures in isolated molecules will be presented, with emphasis directed towards the influence that intramolecular (vibrational and conformational) dynamics and intermolecular (environmental) perturbations can exert on theintrinsic response. Requisite isolated-molecule measurements have been made possible by our development of cavity ring-down polarimetry (CRDP), an ultrasensitive chiroptical probe that has permitted the first quantitative analyses of optical rotatory dispersion (ORD) to be performed in rarefied (gaseous) media. Comparison of specific-rotation values acquired for rigid and flexible chiral species under complementary isolated and solvated conditions will highlight the coupling that exists among electronic and nuclear degrees of freedom as well as the counterintuitive effects incurred by solute-solvent interactions.

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Classe di Scienze Matematiche e Naturali Valeria Giuliani Scuola Normale Superiore Servizio alla Didattica e Allievi tel. 050 509260 Piazza dei Cavalieri, 7 56126 Pisa E-mail: valeria.giuliani@sns.it E-mail: classi@sns.it